Stainless steel

The origins of stainless steel date back to the 19th century, when work began in France on the addition of chromium to carbon steel to protect the material in acidic environments. As such, austenitic steel (with chromium and nickel additions) was patented by German engineers at the Krupp plant.
However, it was not until the early 20th century, when Harry Brearley was working on an alloy to improve the durability of rifle barrel tubes, that the nomenclature of stainless steel began to be used. The Englishman succeeded in this by adding chromium and nickel to the alloy in the right proportions. Practically in parallel to the Englishman's work, a method for the mass production of this steel was developed in France

We are currently dealing with it in almost every area of life. It is widely used in the food, chemical, petrochemical, automotive, construction and many other industries.

Right next to the precise choice of steel grade, of which there are plenty to choose from! (the most common are shown in the table below) for some components, the surface finish is equally important. A surface characterised by greater roughness (with deeper grooves) is more prone to corrosion. as chloride ions can more easily collect in its area and destroy the passive layer.
In contrast, on a polished surface, the same ions have this task made much more difficult. This is why it is so important to precisely define and agree on the favourable characteristics of the surface finish.

Types of stainless steel
due to the crystalline structure

Ferritic steel - owes its name to the ferrite present in its structural structure. The main alloying addition, apart from a small amount of carbon (1.2%), is chromium (11.5-17%). Some grades are also enriched with molybdenum (Mo), titanium (Ti) or niobium (Nb). It is a magnetic steel. It cannot be hardened by heat treatment during production, but can be hardened by cold working.

Application:
automotive, food, oil, coke; chemical industry - and also for the manufacture of kitchen equipment, household appliances and components for photovoltaic assembly.

mono stainless steel ferritic

Austenitic steel - The name refers directly to the structure, i.e. the so-called austenite. It contains up to 0.15 % of carbon and 16-21% of chromium and, above all, a minimum of 8% of nickel (Ni) additives, giving it a high corrosion resistance. This property increases with further alloying additions - such as chromium, molybdenum and titanium. Unlike martensitic steel, austenitic steel is not hardened during the production process. It also has almost twice the elongation values of ferritic steels.

Application:
environments characterised by high temperatures, high humidity, high mechanical stress; used primarily in the chemical and petrochemical industries, construction, aeronautical, railway and shipbuilding, structural engineering or in the manufacture of white goods.

mono austenitic stainless steel

Martensitic steel - Austenitic steel cooled during the production process hardens and acquires a martensitic structure. Although not as corrosion resistant as austenitic and ferritic steels, it has high strength properties and high abrasion resistance. For a stainless steel, it has a relatively high carbon content (0.08 to 0.5%). The chromium content of this steel is 12-17.5%. Martensitic steel is characterised by significantly higher hardness and wear resistance than ferritic steel and austenitic steel, but is difficult to weld. The martensitic structure obtained is magnetic.

Application:
Low-aggressive environments; used primarily to manufacture: screws, springs, pins, pump parts, valves for hydraulic presses, knives, cutting tools, surgical instruments.

mono stainless steel martensitic

Duplex steel - which is a steel with a two-phase ferritic-austenitic structure that contains 16-29% chromium, up to 1.2% carbon, 3.5-8% nickel, 0-4.5% molybdenum and the addition of nitrogen. Duplex steels are steels that retain high corrosion resistance, also in acidic environments. They fulfil at a high level the strength properties that characterise ferritic steels and have a relatively low coefficient of thermal expansion compared to austenitic steels.

Application:
in environments with a high chlorine content (e.g. water desalination, biofuel production, hydraulics - in oil and gas pipelines), as a replacement for austenitic steels in various structures and projects in the food or chemical industries.

Heat-resistant steel - that is steel resistant to the corrosive effects of oxidising gases (chemical corrosion), abrasion and melting in high-temperature environments. The upper limit of heat resistance is between 800 - 1200 degrees C - depending on the composition of the steel grade.

Application:
in environments exposed to fire and/or high temperatures (furnace components, steam boilers, hot gas fans, carburisation boxes, combustion chambers of gas turbines and valves of reciprocating combustion engines)

Stainless steel comparison table
with mechanical properties

STRUCTURE EN PN AISI DIN
PLASTICITY LIMIT Re (Rp0.2)
[N/mm2] min.
TENSILE STRENGTH
Rm [N/mm2]
ELONGATION AT BREAK
A5 [%] min
HB hardness max.
Ferritic 1.4000 0H13 403,410S X6Cr13 230 400-630 19 180
1.4003 - - X2CrNi12 320 450-650 20 180
1.4016 H17 430 X6Cr17 280 450-600 20 160
1.4510 0H17T 439
X3CrTi17 X6CrTi17
240 420-600 23 180
Martensitic 1.4006 1H13 410 X12Cr13 205 <600 20 200
1.4021 2H13 420 X20Cr13 345 <700 15 225
1.4028 3H13 420 X30Cr13 345 <740 15 235
1.4031 4H13 420 X39Cr13 345 <760 12 240
1.4034 4H13 420 X46Cr13 345 <780 12 245
1.4122 3H17M - X39CrMo17-1 - <900 12 280
Austenitic 1.4301 0H18N9 304 X5CrNi18-10 230 540-750 45 215
1.4305 - 303 X8CrNiS18-9 190 520-700 35 190
1.4306 00H18N10 304L X2CrNi19-11 220 520-670 45 200
1.4307 - (304L) X2CrNi18-9 220 520-670 45 200
1.4310 1H18N9 301 X10CrNi18-8 250 600-950 40 215
1.4401 0H17N12M2 316
X5CrNiMo17-12-2
240 530-680 40 215
1.4404 00H17N14M2 316L
X2CrNiMo17-12-2
240 530-680 40 200
1.4435 - 316L
X2CrNiMo18-14-3
240 550-700 40 215
1.4436 - 316
X3CrNiMo17-13-3
240 550-700 40 215
1.4438 - 317L
X2CrNiMo18-15-4
240 550-700 35 215
1.4439 - (317LMN)
X2CrNiMoN17-13-5
290 580-780 35 225
1.4529 - -
X1NiCrMoCuN25-20-7
300 650-850 40 250
1.4539
0H22N24M4TCu
904L
X1NiCrMoCu25-20-5
240 530-730 35 230
1.4541
0H18N10T 1H18N9T 1H18N10T
321
X6CrNiTi18-10
220 520-720 40 215
1.4547 - -
X1CrNiMoCuN20-18-7
320 650-850 35 225
1.4550 0H18N12Nb 347
X6CrNiNb18-10
220 520-720 40 230
1.4571
H17N13M2T H18N10MT
316Ti
X6CrNiMoTi17-12-2
240 540-690 40 215
Duplex 1.4362 - 2304 X2CrNiN23-4 450 600-850 20 290
1.4410 - 2507
X2CrNiMoN25-7-4
550 750-1000 15 310
1.4460 - 329
X3CrNiMoN27-5-2
460 620-880 20 260
1.4462 - 2205
X2CrNiMoN22-5-3
500 660-950 20 293

The data in the table above is indicative.

Comparison of the properties of stainless steels

TYPE OF STEEL MAGNETICITY CORROSION RESISTANCE CONTINUITY RESISTANCE SPAWARABILITY
ferritic yes average average high low
martensitic yes average low average low
austenitic not high very high very high very high
duplex yes very high average low high
heat-resistant yes average average high high

 

Differences between cold-rolled sheets
and hot-rolled

PROPERTIES COLD-ROLLED SHEET HOT-ROLLED SHEET
HEAT TREATMENT the recrystallisation temperature is approx. 600°C the recrystallisation temperature is on average 600°C and the process temperature as high as 1300°C
APPLICATION industrial sector:
production of thin sheets and strips, films and tubes
or small diameter rods
automotive industry
white goods industry
electronics industry
industrial sector:
in the manufacture of thick sheets
which are structural elements of bridges,
machinery, containers or vehicles
FAILURES harder to process further slightly alters the previous strength properties
BENEFITS increased strength, without significant deterioration in plastic properties
smooth, finely finished surface
speed and high efficiency thanks to surface treatment
has high ductility and malleability
improved steel grain size and therefore better mechanical properties of the material
easy to process further
NOTES However, cold and hot rolling of sheet metal involves the development of inherent stresses in the metal parts.
Even at low processing temperatures, there is a risk of unwanted warping, deformation or cracking of the sheet, depending on the force used for plastic forming.

 

Stainless steel corrugated sheets

DIN 59220

ASTM A793 - Pattern B

 

Basic surface finishes of stainless steel sheets

DISCLAIMER SHEET TYPE DESCRIPTION
1D HOT-ROLLED SHEET Scale-free surface. The most common finish, with the highest corrosion resistance.
2B COLD-ROLLED SHEET The most popular cold-rolled finish. Smooth, retains flatness well. Finish used for further processing.
2R / BA POLISHED SHEET Mirrored surface, very smooth. Often protected by a film.
240 / 320 / 4MN / DUPLO GROUND SHEET Unidirectional surface texture, poorly reflective.

 

Seamless pipes

EN 10216-5 - pipes for pressure applications,

EN 102297-2 - pipes for mechanical and general technical applications,

 

Structural tubes (welded)

Structural tubes (EN 10296-2):

Weld factor V=0.8*,

Surface: raw, ground, polished

Installation pipes (EN 10217-7) - these are structural pipes that have passed destructive tests, this means that the strength around the circumference is the same:

Weld factor V=1*,

Certificate 3.1,

Surface: raw, ground, polished and etched

Food pipes - these are pipes designed for the food industry, the internal seam removed, the internal surface of the pipe must be perfectly smooth,

*V - is the ratio of the weld strength to the pipe material strength
(V=1 means that the strength of the pipe around its circumference is the same)

Perforated sheets

Perforated sheets are manufactured from the highest quality stainless steel, acid resistant, aluminium, brass and copper. They are characterised by durability, lightness and universality of application. They are used in the engineering, food, agricultural and construction industries and as decorative elements.

Holes are made in various shapes, including: circular, cylindrical, conical, conical-cylindrical, square, rectangular, hexagonal, bowl-shaped, elongated and others according to individual designs.

Due to their widespread decorative use, perforated sheets are often covered with protective and decorative coatings.

Rv

Round holes,
60° passing system

rg

Round holes,
straight 90° system

rd

Round holes,
45° diagonal arrangement

qg

Square holes,
straight 90° system

qv

Square holes,
60° passing system

qd

Square holes,
45° diagonal arrangement

lv

Longitudinal openings,
system passed

lg

Longitudinal openings,
simple system

hv

Hexagonal holes,
hexagonal,
60° passing system

deco

Holes
decorative

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